VMCD (Vista Media Center Decoder Utility)
Search for it online, download and save it to your desktop, after saving run it and in the drop down you should see your decoder options, select the one you want as your default as well as you audio decoder.
As far as Divx, I just installed it, didn't install the Koepi
Are you using RC1 drivers from ATI's site, when I tried using those I had a problem watching videos due to vista not recognizing it with the RC1 drivers, but once I uninstalled and went back to the RC2 drivers that came with Vista 5744, all worked fine, but I had to use Nvidia Purevideo Decoder to get the Live tv to work without stutter.
Hope this helps
System Specs:
Pentium 4 Processor 3.06GHz
2 GB RAM
GForce 8500 GT 512Mb
Hauppauge WinTV-HVR-1800
Creative X-Fi XtremeGamer
42 inch Samsung Series 5 HDMI
Windows 7 System Rating 4.0