Thank you for telling me that. I now have the knowledge to do so and I shall share it.
Now I just have to master making a thumbnail for it and making it show up.
Adding Windows-based
Applications
You can add any Windows-based application to the Media Center More Programs
page by placing a shortcut to it in the following folder:
C:\Documents and Settings\User folder\Start Menu\Programs
\Accessories\Media Center\Media Center Programs
In this path, "User folder" can be either the All Users folder or the folder
of the current user, whichever is appropriate. The name of the shortcut should
be the name of your application, with no "shortcut_to_" prefix, and with the
extension .lnk; for example, MyApplication.lnk. The name of the shortcut, minus
the .lnk extension, is displayed as the button label on the Media Center More
Programs page.
Adding an application to the Media Center More Programs page also causes it
to be added to the Media Center Start page menu.